Gettin' Stiff

Although the development of rigor mortis is highly variable, rigor is usually well established throughout the body some twelve hours after death and resolved within thirty hours. It develops in the smaller muscles of the face and neck first (eyelids, jaws), spreads to larger muscle groups, and then towards the feet.
Rigor mortis is due to the decomposition of ATP (adenosine triphosphate), which is required for muscle contraction. When the ATP is completely gone (about four hours after death), the muscle becomes regid and remains stiff until actual decomposition occurs. If there has been violent exertion shortly before death (i.e., struggle with an attacker, suffocation, drowning, electrocution), the development or rigor mortis is speeded up since the ATP resource is already depleted. On the contrary, is the death is non-violent (carbon monoxide poisoning, etc...), the process is delayed because ATP reserves are still available.
NOTE: rigor mortis is a poor indicator of time of death since there are large numbers of variables - activity at time of death, environmental temperature, and physical characteristics of the decease. Very obese people may never develop rigor mortis, while skinny blokes develop it rapidly. Heat speeds it up, cold retards the process.

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